Breaking the Perfluorooctane Sulfonate Chain: Piezocatalytic Decomposition of PFOS Using BaTiO3 Nanoparticles

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Read the full article in the following link: https://zenodo.org/records/14011708


Andrea VecianaSarah SteinerQiao TangVitaly PustovalovJoaquin Llacer-WintleJiang WuXiang-Zhong ChenTrust ManyiwaVenecio U. Ultra Jr.Beltzane Garcia-CireraJosep Puigmartí-LuisCarlos FrancoDavid J. JanssenLaura NyströmSamy BoulosSalvador Pané


Per- and polyfluoroalkyl substances (PFAS) pose significant environmental and health risks due to their ubiquitous presence and persistence in water systems.Herein, the efficacy of piezocatalysis using barium titanate nanoparticles underultrasound irradiation for the degradation and defluorination of perfluorooctanesulfonate (PFOS) in water is investigated. The research demonstrates a sub-stantial 90.5% degradation and 29% defluorination of PFOS after 6 h of treat-ment, highlighting the potential of piezocatalysis as a promising approach forPFAS degradation. Additionally, the quantification of degradation products elucidates the transformation pathways of PFOS, suggesting a stepwise chain-shortening mechanism. The findings underscore the importance of continued research in optimizing piezocatalytic processes and exploring synergistic approaches with other advanced oxidation methods to effectively address PFAScontamination challenges. These efforts are essential for advancing sustainable water treatment strategies and mitigating the environmental and health hazards associated with PFAS contamination.

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